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Risorse bibliografiche
Risorsa bibliografica obbligatoria
Risorsa bibliografica facoltativa
Scheda Riassuntiva
Anno Accademico 2016/2017
Scuola Scuola di Ingegneria Industriale e dell'Informazione
Insegnamento 096243 - ADVANCED CHEMISTRY FOR MATERIALS ENGINEERING
  • 096242 - STRUCTURAL CHEMISTRY OF MATERIALS
Docente Raos Guido
Cfu 5.00 Tipo insegnamento Modulo Di Corso Strutturato

Corso di Studi Codice Piano di Studio preventivamente approvato Da (compreso) A (escluso) Insegnamento
Ing Ind - Inf (Mag.)(ord. 270) - MI (491) MATERIALS ENGINEERING AND NANOTECHNOLOGY - INGEGNERIA DEI MATERIALI E DELLE NANOTECNOLOGIE*AZZZZ096243 - ADVANCED CHEMISTRY FOR MATERIALS ENGINEERING

Programma dettagliato e risultati di apprendimento attesi

Course objectives

Review fundamental chemistry (and physics) concepts: bonding, molecular structure and reactivity using approximate models, often developed for specific purposes.

Complement the study of key, but neglected, areas of chemistry: expand scope to some main group inorganic and to d–metal chemistry and materials (also organometallics).

Outline relevance of these topics to materials engineering & science: examples of hybrid and nanostructured materials (layered structures, highly porous MOF’s, transition metal catalysts, etc.).

Course program

Summary of atomic structure, periodic properties and molecular structure. Lewis structures, VSEPR model and Valence Bond theory. Elements of molecular orbital theory. Applications of the above concepts to the description simple inorganic and organic compounds (e.g., summary of the main functional groups).

Molecular symmetry: point groups, irreducible representations and character tables. Applications of symmetry concepts to molecular orbitals.

Lewis acids and bases: classification of reactions, hardness and softness, acidity parameters. Electrophilic and nucleophilic species in organic chemistry.

Chemistry of selected main group elements (e.g.: 1st, 2nd, 14th, 15th).

Introduction to the chemistry of transition metals. Structure and thermodynamics of coordination complexes. Crystal field and ligand field theories. Organometallic compounds. Polymerization catalysts.

Structure and symmetry of crystalline solids. Description and rationalization of representative inorganic crystal structures (metals, ionic and covalent solids). Defects. Metal oxides, nitrides and fluorides. Framework structures. Hydrides and hydrogen storage materials. Semiconductor chemistry. Molecular materials. Polymer crystal structures.

Computer practicals

Classroom exercises illustrating the use of scientific software for: (a) molecular orbital calculations (b) visualization of crystal structures.

Prerequisites and tutorials

During the first weeks of the course, there will be a series of additional, optional tutorials. The aim of the tutorials is to provide a revision of some introductory chemistry concepts, which are usually taught in first year engineering courses:

1. The periodic table. Metals, non-metals and their oxides. Oxidation numbers. The mole.

2. Elementary reactions in water. Dissolution and precipitation reactions. Arrhenius acids and bases. Red-ox reactions.

3. Applications of the above concepts and stoichiometric calculations.

4. Lewis structures. Geometry and polarity of molecules.

5. Thermochemistry. Enthalpy and heat of reactions.

6. Entropy and Gibbs free energy. Chemical equilibrium and equilibrium constants.

7. Electrochemical cells. Electromotive force. Simple corrosion reactions.

Knowledge of the above topics represents a prerequisite for successfully attending the course.

Course slides and material

Slides and additional material for the course will be available through the BEEP web site: https://beep.metid.polimi.it/

 


Note Sulla Modalità di valutazione

The exam will consist of a written test concerning the whole program (both open theory questions and numerical exercises). The exam may be taken in February (two separate tests), or July (two tests) or September (two tests). The students may take an optional oral exam, for written evaluations starting from 15/30 (maximum change ±3 points).

The final score of the Advanced Chemistry for Materials Engineering course (10 CFU) will be averaged with the results of the module taught by Prof. S. Turri (Principles of Polymer Chemistry). The Advanced Chemistry for Materials Engineering (10 CFU) exam is passed and registered when the mark is at least 16/30 in both modules. The two modules may be taken separately (i.e. in two different exam sessions), but both modules must be passed during the same academic year (i.e. within the February session of the following year).


Bibliografia
Risorsa bibliografica obbligatoriaWeller, Overon, Rourke, Armstrong, Inorganic Chemistry, 6th edition, Editore: Oxford University Press, Anno edizione: 2014, ISBN: 019964182X
Note:

Also ealier editions (named Shriver and Atkins' Inganic Chemistry) are okay

Risorsa bibliografica facoltativaAnthony West, Solid State Chemistry and its Applications, 2nd Edition: Student Edition, Editore: Wiley, Anno edizione: 2014, ISBN: 978-1119942948
Risorsa bibliografica facoltativaWikipedia https://en.wikipedia.org/wiki/Portal:Chemistry

Mix Forme Didattiche
Tipo Forma Didattica Ore didattiche
lezione
32.0
esercitazione
16.0
laboratorio informatico
0.0
laboratorio sperimentale
0.0
progetto
0.0
laboratorio di progetto
0.0

Informazioni in lingua inglese a supporto dell'internazionalizzazione
Insegnamento erogato in lingua Inglese
Disponibilità di materiale didattico/slides in lingua inglese
Disponibilità di libri di testo/bibliografia in lingua inglese
Possibilità di sostenere l'esame in lingua inglese
Disponibilità di supporto didattico in lingua inglese
schedaincarico v. 1.6.4 / 1.6.4
Area Servizi ICT
10/07/2020