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Risorsa bibliografica obbligatoria |
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Risorsa bibliografica facoltativa |
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Anno Accademico
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2017/2018
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Scuola
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Scuola di Ingegneria Industriale e dell'Informazione |
Insegnamento
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099300 - SOFT MATTER: THE STRUCTURE AND RHEOLOGY OF COMPLEX FLUIDS
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Docente |
Buzzaccaro Stefano
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Cfu |
5.00
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Tipo insegnamento
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Monodisciplinare
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Corso di Studi |
Codice Piano di Studio preventivamente approvato |
Da (compreso) |
A (escluso) |
Insegnamento |
Ing Ind - Inf (1 liv.)(ord. 270) - MI (347) INGEGNERIA CHIMICA | * | A | ZZZZ | 099300 - SOFT MATTER: THE STRUCTURE AND RHEOLOGY OF COMPLEX FLUIDS | Ing Ind - Inf (Mag.)(ord. 270) - MI (472) CHEMICAL ENGINEERING - INGEGNERIA CHIMICA | * | A | ZZZZ | 099300 - SOFT MATTER: THE STRUCTURE AND RHEOLOGY OF COMPLEX FLUIDS | Ing Ind - Inf (Mag.)(ord. 270) - MI (491) MATERIALS ENGINEERING AND NANOTECHNOLOGY - INGEGNERIA DEI MATERIALI E DELLE NANOTECNOLOGIE | * | A | ZZZZ | 099300 - SOFT MATTER: THE STRUCTURE AND RHEOLOGY OF COMPLEX FLUIDS |
Programma dettagliato e risultati di apprendimento attesi |
The course is an introduction to the physics of soft materials, complex fluids, and biological systems, ranging from simple colloidal suspensions to polymer, spontaneous surfactant aggregates, gels, proteins and nucleic acids. Besides providing a bottom-up presentation of the properties of complex fluids, based on their microscopic structure and interactions, the course aims at highlighting the important practical applications of these materials in the general market and for nanotechnologies. In particular, we review the most basic distinctions and similarities among the rheological (or flow) properties of various complex fluids, highlighting how the microstructure and microstructural forces control their rheological properties.
General introduction to disperse systems and supramolecular systems. Review of statistical thermodynamics. Dilute suspensions and osmotic pressure. Effective forces between dispersed particles: excluded volume, van der Waals and electrostatic interactions, depletion forces. Brownian motion.
Colloidal dispersions. Stability of a suspension of colloidal particles and colloidal aggregation. Colloidal crystals, glasses and hydro/aerogels. Patchy particles. Active colloids. Applications of nanofluids in nanotechnology.
Polymer solutions. Dilute solutions and polymer coils. Semi-dilute solutions, polymer meshes, and Flory-Huggins theory. Polymer gels. Polyelectrolytes.
Surfactant solutions and Emulsions. Classes of surfactant and their practical applications. Micellization and basic principles of detergency. Self-assembly of surfactant molecules: micelles, “living polymers”, inverted micelles, and vesicles. Emulsion stability. Micro and Nano Emulsion. Pickering Emulsions.
Biological fluids. Protein structure. Enzymes and biocatalysis. Transport, structural, and membrane proteins. Protein crystallization. Molecular machines.
Rheological Measurements and Properties of complex fluids. Shear Thinning and Shear Thickening in hard sphere systems. Rheology of particulate gels. Rheology of Dilute Polymer Solutions. Rheology of entanlged polymers. Rheology of glassy liquids. Rheology of surfactants: spherical vs worm-like micelles.
Experimental methods to investigate soft and biological materials. Light Scattering, correlation spectroscopy, video microscopy, and microfluidics techniques (with lab presentations). Macro and micro-rheology.
All these arguments are treated in the lectures notes accessible on the Beep platform to the students participating to the course, wherefrom several good review papers on soft and biological matter can also be freely downloaded.
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Note Sulla Modalità di valutazione |
The course is organized as a series standard classroom lectures, in which the main theoretical arguments are developed, supported by the discussion of specific applications, to be regarded as exercitations. The final test consists of a traditional oral exam.
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Roberto Piazza, Soft Matter: The Stuff That Dreams Are Made of , Editore: Springer Verlag, Anno edizione: 2011, ISBN: 978-9400705845 Note:This is not a textbook, but rather a popoular science book written in a plain language and accessible to a large audience. Yet, it contains most of the physics we need
Coussot, Philippe, Rheophysics, Editore: Springer International Publishing, Anno edizione: 2014, ISBN: 978-3-319-38016-2 Note:This book presents a unified view of the physicochemical origin of the mechanical behaviour of soft materials.The mathematical formalism is reduced in order to focus on physical explanations.
R.G. Larson, The Structure and Rheology of Complex Fluids, Editore: Oxford University Press, Anno edizione: 1999, ISBN: 978-0-19-512197-1 Note:A bit technical, but a good starting point for appreciating the physics and dynamics of complex fluids.
R. A. L. Jones, Soft Condensed Matter, Editore: Oxford University Press, Anno edizione: 2002, ISBN: 978-0198505891 Note:A slim and accessible introduction, although at a level which is not as advanced as the one of this course
T. A. Witten,, Structured Fluids, Editore: Oxford University Press, Anno edizione: 2010, ISBN: 978-0199583829 Note:A very good book, at a level a bit more advanced than the one of this course, and with a more theoretical lingo
Philip Nelson, Biological Physics, Editore: W. H. Freeman, Anno edizione: 2007, ISBN: 978-0716798972 Note:One of the best introduction to biophysics
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Nessun software richiesto |
Tipo Forma Didattica
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Ore didattiche |
lezione
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30.0
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esercitazione
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20.0
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laboratorio informatico
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0.0
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laboratorio sperimentale
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0.0
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progetto
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0.0
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laboratorio di progetto
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0.0
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Informazioni in lingua inglese a supporto dell'internazionalizzazione |
Insegnamento erogato in lingua

Inglese
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Disponibilità di materiale didattico/slides in lingua inglese
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Disponibilità di libri di testo/bibliografia in lingua inglese
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Possibilità di sostenere l'esame in lingua inglese
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Disponibilità di supporto didattico in lingua inglese
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